N-PROPANOL

I. CHEMICAL PRODUCT IDENTIFICATION

Product Name	:	n-propanol
Usefulness	:	The main application is as a solvent in flexographic and printing inks. In the coating industry, n-propanol is used to improve the drying characteristics such as for alkyd resins, paints and settlement electrodeposisi baking. This material is added to the cleaners, pengkilat floor, and the liquid metal degreasing, and is used as an additional solvent in the manufacture of adhesives. n-propanol is also in de-icing fluid and used as ekstaktan in Azeotropic distillation.n-propanol is also a feedstock in the manufacture of insecticides, herbicides and pharmaceuticals.

II. ABOUT CHEMICAL MATERIAL

Material Identification	:	Propan-1-ol
Chemical Family	:	Alcohol
Synonym	:	n-propanol
		1-propanol
		n-propyl alcohol
		Ethyl carbinol
		propylic alcohol
		1-Hydroxypropane
Molecular formula	:	C 3 H 8 O
CAS Number	:	71-23-8
UN Number	:	1274
EC number	:	200-746-9
Hazard Symbols	:	M & Xi
Risk Phrases	:	R11 R41 R67
Danger Phrase	:	S2 S7 S33 S24/25 S36/37/39 s16
Form	:	Liquid
Color	:	Clear
Odor	:	The smell of alcohol
Boiling point	:	95-99 o C
Freezing point	:	- 127 o C
Flash point	:	25 o C (Closed Cup)
Auto ignition temperature	:	440 o C
Explosion limit	:	2.1 - 13.5 vol%
Vapor pressure	:	4.13 mmHg @ 21oC
Vapor density (relative to air)	:	2:07
Specific Gravity	:	0.8000 - 0.8100 (20 o C)
Average evaporation	:	1 (ASTM 3539, nBuAc = 1)
Solubility in water (25 o C)	:	Total

For the full text of risk phrases and hazard phrases mentioned in this chapter, see chapter XIV

III. HAZARD IDENTIFICATION

F = Flammable

Xi = Irritant

Safety hazard

Fluid and highly flammable vapors. Mixture with air can form an explosive. Vapor is heavier than air and can move along the ground toward the distant ignition source and can be lit.

Potential health hazards

Harmful if swallowed, inhaled or absorbed through the skin. Can affect the central nervous system. Irritating to skin, eyes and respiratory tract. Aspiration may cause lung damage.

IV. SELF PROTECTION GEAR

Standard exposure	:	American Conference of Governmental Industrial Hygienists (ACGIH)
		n-propanol: TWA - 200 ppm
		TWA is the concentration average based on time (time-weighted average) for a normal 8-hour workday or 40 hours per-week when nearly all workers can be exposed to direct repeatedly without adverse effects
Respiratory Protection	:	If inadequate ventilation use suitable respiratory equipment.
Skin and body protection	:	Chemical resistant protective clothing appropriate including boots, gloves, lab coat, apron should be used to prevent contact with skin.
Eye protection	:	Avoid contact with eyes by using chemical Goggles with side protection or face protection when there is exposure to steam or fog, or if there is a risk of liquid splashing into the eyes. Safety showerand eyewash must be provided in all areas where this material is handled.

FIRST AID ACT V.

General advice	:	If symptoms continue or if in doubt, ask for medical help immediately.
Inhalation	:	Move victim to fresh valve. If there are symptoms of cough or respiratory problems lainnyasegera provide medical care. If not breathing give artificial respiration, if breathing is difficult give oxygen.Immediately contact your doctor.
If contact with skin	:	Wash immediately with soap and plenty of water, removing contaminated clothing and shoes. Wash contaminated clothing separately. If irritation persists, contact your doctor immediately.
If contact with eyes	:	Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
If swallowed	:	Rinse mouth with water. If the victim unconscious and awake, give 1-2 glasses of water or milk. Do not try vomiting unless dibiimbing by medical personnel because of the risk of lung damage. Never give anything by mouth to an unconscious victim or seizures. Immediately contact your doctor.

VI. FIRE ACTION Fighting

Flash point	:	25 o C (Closed Cup)
Auto ignition temperature	:	440 o C
Explosion limit	:	2.1 - 13.5 vol%
Fire Extinguisher	:	Water spray, alcohol resistant foams, dry chemical, carbon dioxide.
Means of extinguishing fires that do not fit	:	Torrential water flow
Fire fighting procedures	:	Use water to cool containers exposed to fire. Heating may cause expansion or decomposition that can result in container rupture. If safe, remove containers from path of fire. Spills and leaks can be doused with water, or mist in large quantities. Spills and leaks can be diluted with water to a mixture which can neither flammable.
Special protective equipment for firefighters	:	At the time of extinguishing fires, use full protective clothing with breathing equipment such as self-contained breathing apparatus operated in positive pressure.

VII. Dealing With The leakage

Self protection	:	Do not breathe vapor or mist. Avoid contact with the material spilled or leaked. Use appropriate personal protective equipment. Turn off all sources of ignition. Ventilasikan area. Keep the people who are not concerned of leakage area.
Environmental Protection	:	Avoid contamination of water into the sewer, water wells atausaluran. If contamination to wells or waterways has occurred, immediately notify the appropriate authorities.
Methods for cleaning	:	For small leaks
		Use water spray to reduce vapors and assemble it with sand or other absorbent material (soil, vermiculite, silica gel) and enclosed in kontaineryang sealed for safe disposal.
	:	For large leaks
		Weir leakage for further disposal. Do not smoke, do not have a flame apidi danger area.Ventilasikan leakage area. If possible, the spilled liquid is pumped or transferred kekontainer waste. The residual liquid is absorbed, and must be contained in separate containers. Disposal must be carried out following the laws and regulations.

VIII. Handling AND STORAGE

Handling	:	Use only in well-ventilated area and away darisumber ignition. Use equipment safely in certain areas where this material is used. Do not use pressure to compressed udar for charging, transferring, mixing or handling because of the danger of steam. Containers must be earthed (earthed) to avoid static charge when the agitation process or product transfer.
Storage	:	Store in a closed container in a cool place, well-ventilated isolated and away from heat, ignition sources and incompatible materials. Keep away from oxidizing materials. Always close the container tightly - check regularly to leakage. Do not eat, drink or smoke in the area of use or storage.

IX. AND REACTIVITY Stability

Stability	:	Stable under conditions of normal use and storage.
Conditions to be avoided	:	Heat, ignition sources (flame, sparks, static charge), incompatible materials.
Inappropriate materials	:	Strong oxidizing materials, strong acids, strong bases, amines, halogenated compounds.
Hazardous polymerization	:	Will not occur.
Hazardous decomposition products	:	Carbon dioxide and carbon monoxide can be formed when incomplete combustion occurs.

X. TOXICOLOGICAL INFORMATION

Acute Toxicity
Acute oral poison		:	LD50 rat: 8038 mg / kg of
Acute inhalation poisons		:	LC50 rat:> 33.8 ppm (4 hours)
Acute dermal poison		:	Rabbit LD50: 4049 mg / kg
Effects on humans
Inhalation		:	May cause respiratory tract irritation. Steam can cause drowsiness and dizziness. Inhaling vapors in high concentrations can cause central nervous system depression and narcosis.
If swallowed		:	Can be harmful if swallowed. May cause gastrointestinal irritation, nausea, vomiting and diarrhea.May cause systemic toxic effects with symptoms similar to inhalation.
If contact with skin		:	Can irritate the skin. Can be harmful if absorbed through the skin, causing systemic toxic effects with symptoms similar to inhalation.
If contact with eyes		:	Liquid and vapor can cause irritation and severe damage to the eye. Steam can cause mild eye irritation at concentrations above 400 ppm.
Chronic Exposure		:	Prolonged contact with skin and may cause the removal of fat over the skin resulting in dry trowel, reddened and possibly blister. Exposure to prolonged and repeated material can cause liver and kidney damage.

XI. Ecological INFORMATION

Decomposition by the environmental			:	This material is easily explained by environmental
Ecotoxicity			:	Toxicity to fish: LC50 (48 hours): <4000 mg / L, Golden Orfe
				Toxicity to daphnia: EC50 (48 hours): 3642 mg / L, Daphnia magna
Bioaccumulation			:	Not expected to significantly bioaccumulated.
Mobility			:	This material does not easily evaporate and dissolve in water.

XII. Disposal

Product Disposal	:	This material must be enclosed and should not be dumped in rivers, drains or waterways.Reproduction of this material to dispose of remaining in environmental media, without prior treatment in accordance with the Government Regulation no. 18th Year of 1999 on Management of Hazardous and Toxic Waste
Disposal containers	:	Empty containers should be cleaned by rinsing with water. Containers that can not be used again should be cleaned from the steam-vapor prior to disposal. Residues may cause an explosion hazard Do not punch a hole, cutting or welding drums that have not been cleaned.Left empty packaging should be used initially or discarded after the Government Regulation No. 18 Year 1999 regarding Management of Hazardous and Toxic Waste
Local Regulations		Combustion can be performed by a body approved under controlled conditions if permitted by the authorities, if not removal should be done following the rules on waste and environmental regulations.

XIII. Transportation Method

Ground transportation		:	UN number		: 1274
			Class		: 3
			Packing Group		: II
Marine transportation		:	UN number		: 1274
			Class		: 3
			Packing Group		: II
Air Transport		:	UN number		: 1274
			Class		: 3
			Packing Group		: II

XIV. INFO RELATING TO REGULATION

Symbol		:	M - Highly flammable
			Xi - Irritating
Risk Phrases			R 11	Highly flammable
			R 41	Risk of serious damage to eyes
			R 67	Steam can cause drowsiness and dizziness.
Safety phrase		:	S 2	Keep out of reach of children
			S 7	Close the container tightly
			S 16	Keep away from sources of ignition - no smoking.
			S 24/25	Avoid contact with skin and eyes
			33 S	Take precautions against the occurrence of static electricity jump.
			S 36/37/39	Wear protective clothing / gloves and eye protection / face accordingly.