I. CHEMICAL PRODUCT IDENTIFICATION
| Product Name | : | Benzyl alcohol | |||||
| Usefulness | : | Benzyl alcohol used as solvent for printing ink, paint, lacquer and epoxy resin coating.Benzyl alcohol is also used as precursors for making various kinds of esters, used in soap, perfume, and taste the food industry. These materials are also often added in a solution of the drug to the blood vessels caused by anti-bacteria properties. | |||||
II. ABOUT CHEMICAL MATERIAL
| Material Identification | : | Benzyl alcohol | |||||||
| Chemical Family | : | Aromatic alcohol | |||||||
| Synonym | : | Benzal alcohol | |||||||
| Benzene carbinol | |||||||||
| Benzene methanol | |||||||||
| alpha-hydroxytoluene | |||||||||
| : | Benzoyl alcohol | ||||||||
| : | Phenylmethanol | ||||||||
| : | Phenylcarbinol | ||||||||
| Molecular formula | : | C 7 H 8 O | |||||||
| CAS Number | : | 100-51-6 | |||||||
| UN Number | : | - | |||||||
| EC number | : | 202-859-9 | |||||||
| Hazard Symbols | : | Xn | |||||||
| Risk Phrases | : | R 20/21/22 R 36/37/38 | |||||||
| Danger Phrase | : | S 24/25 S 26 S 36/37/39 | |||||||
| Form | : | Liquid | |||||||
| Color | : | Clear | |||||||
| Odor | : | Slightly aromatic odor | |||||||
| Boiling point | : | 205 o C | |||||||
| Melting point | : | -15 O C | |||||||
| Flash point | : | 93 o C (closed cup) | |||||||
| Auto ignition temperature | : | 436 o C | |||||||
| Explosion limit | : | - | |||||||
| Vapor pressure | : | 0:15 mmHg @ 25 o C | |||||||
| Vapor density (relative to air) | : | 3.72 | |||||||
| Specific Gravity | : | 1042-1047 (25 o C) | |||||||
| Evaporation time | : | <0:01 (ASTM 3539, nBuAc = 1) | |||||||
| Solubility in water | : | 42.9 g / l @ 25 o C | |||||||
For the full text of risk phrases and hazard phrases mentioned in this chapter, see chapter XV
III. HAZARD IDENTIFICATION
 |
| Xn = Dangerous |
| Safety hazard | ||||||||
| Combustible liquid and vapor | ||||||||
| Potential health hazards | ||||||||
| May cause severe eye irritation. Exposure to vapors can cause headaches, dizziness and nausea. Excessive exposure can cause central nervous system depression. Can cause skin irritation. | ||||||||
IV. SELF PROTECTION GEAR
| Standard exposure | : | American Industrial Hygiene Association (AIHA) | ||
| Benzyl alcohol: TWA - 10 ppm | ||||
| TWA is the concentration average based on time (time-weighted average) for a normal 8-hour workday or 40 hours per-week when nearly all workers can be directly exposed repeatedly without adverse effects. | ||||
| Respiratory Protection | : | Bila ventilasi tidak mencukupi, pakai peralatan pernafasan yang sesuai. | ||
| Skin and body protection | : | Wear clothes that do not penetrate the protection chemicals, including boots, gloves, lab coat, full of evil clothing (apron) as appropriate, to prevent contact with skin. | ||
| Eye protection | : | Wear chemical goggles (chemical safety Goggles) and / or full face protection if splashing is possible the existence of this material. Place an emergency shower and eye washing facilities(eyewash) should be available in the workspace. | ||
V. FIRST AID ACT
| General advice | : | If symptoms continue or if in doubt, ask for medical help immediately. | |
| Inhalation | : | Move victim to fresh valve area. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Provide medical help immediately. | |
| If contact with skin | : | Immediately flush skin with large amounts of water for at least 15 minutes. Remove contaminated clothing and shoes. Give medical aid. Wash clothing and shoes before reuse | |
| If contact with eyes | : | Immediately flush with plenty of water for at least 15 minutes with open eyelid. Provide medical help immediately. | |
| If swallowed | : | Give plenty of water to drink. Never give anything by mouth to an unconscious victim. Give medical aid. | |
VI. FIRE ACTION Fighting
| Flash point | : | 93 o C (closed cup) | |||||||
| Auto ignition temperature | : | 436 o C | |||||||
| Explosion limit | : | - | |||||||
| Facility fire | : | Dry chemical, foam or carbon dioxide. Water spray can be used to cool containers exposed to fire surface. | |||||||
| Means of extinguishing fires that do not conform | : | Do not use heavy water flow (because it can scatter and spread fire). | |||||||
| Fire fighting procedures | : | Use carbon dioxide, foam, or dry chemical to extinguish fires. Water can be used to cool the fire, but to extinction, foam or dry chemicals better. Prevent the spread of flames by fluid and flooded with water.Wear full protective clothing and full respiratory protection equipment. Use water to cool containers. | |||||||
| Special protective equipment for firefighters | : | Wear full protective clothing and full respiratory protection equipment. | |||||||
VII. Dealing With The leakage
| Self Protection | : | Wear appropriate personal protective equipment. Prevent people who are not on duty and not wearing protective equipment to not enter the area of leakage. | ||
| Environmental Protection | : | Do not be dumped into waterways or drainage systems without appropriate authorization.Collect contaminated water and firefighters used water, for further disposal in accordance with applicable regulations | ||
| Methods for cleaning | : | For small leaks | ||
| Dilute with water and cloth or absorb with an inert absorbent material is dried and enclosed in a container that is suitable for further disposal. Complete the cleaning by rinsing with water contaminated surface and dispose of according to local and regional regulations accordingly. | ||||
| For large leaks | ||||
| Combustible materials. Keep away from heat. Keep away from ignition sources. Close the leak if possible without risk. Complete the cleaning by rinsing with water contaminated surface and dispose of according to local and regional regulations accordingly. | ||||
VIII. Handling AND STORAGE
| Handling | : | Bumikan (ground) all equipment. Do not swallow this material. Do not breathe gas / fumes / vapor / spray. If there is no adequate ventilation, use suitable respiratory equipment. Wear appropriate protective clothing. Avoid contact with skin and eyes. |
| Storage | : | Keep container in a cool place and well ventilated. Cover tightly and seal the container until ready for use. Avoid all sources of ignition (spark or flame). This material is sensitive to light. Store in light-resistant container. |
IX. AND REACTIVITY Stability
| Stability | : | This material is stable under conditions of normal use and storage. May experience a slow oxidation reaction if there is air or oxygen and produce benzaldehyde and benzoic acid. | ||
| Conditions to be avoided | : | Heat, flames, ignition sources and incompatible materials. | ||
| Inappropriate materials | : | Acids, oxidizing materials, aluminum. This material may attack some plastics. | ||
| Hazardous polymerization | : | When heated above 100 o C, Benzyl alcohol containing hydrogen bromide and dissolved iron can polymerizes rapidly with rising temperature. | ||
| Hazardous decomposition products | : | Carbon dioxide and carbon monoxide can be produced when the material is heated to decompose. | ||
X. TOXICOLOGICAL INFORMATION
| Acute Toxicity | ||||||||
| Acute oral poison | : | LD50 rat: 1230 mg / kg | ||||||
| Acute inhalation poisons | : | Rat LC50: 1000 ppm / 8 hours | ||||||
| Acute dermal poison | : | Rabbit LD50: 2000 mg / kg | ||||||
| Effects on humans | ||||||||
| Inhalation | : | May cause respiratory tract irritation. Symptoms may include coughing, shortness of breath. It can be absorbed into the bloodstream and cause the same symptoms are like if swallowed. | ||||||
| When the affected eye | : | Can cause irritation, red eyes and sore. May cause eye damage. | ||||||
| If contact with skin | : | Can cause skin irritation, redness, pain and injury on the network. Can be absorbed through the skin with symptoms such as when swallowed. And long-term exposure can cause any known repeated allergic reactions and dernatitis. | ||||||
| If swallowed | : | Harmful if swallowed. Ingestion of large amounts may cause abdominal pain, nausea, vomiting and diarrhea. May affect behavior / central nervous system and cause headaches, dizziness, coma, convulsions and depression symptoms of other central nervous system. Can also affect the respiratory (paralysis of respiratory center, respiratory depression), cardiovascular system (hypotension). Ingestion in the long term and repetitive behavior can affect / central nervous system with symptoms such as has been mentioned. Can also affect the liver, kidneys, cardiovascular system and metabolism. | ||||||
XI. Ecological INFORMATION
| Decomposition by the environmental persistence and | : | This material is easily explained by environmental | ||
| Ecotoxicity | : | LC50: 770 mg / l 48 hours, Pimephales promelas | ||
| LC50: 10 ppm 96 hours, Lepomis macrochirus | ||||
| LC50: 15 ppm 96 hours, Menidia beryllina | ||||
| Bioaccumulation | : | This material is not expected to significantly berbioakumulasi | ||
| Mobility | : | When he was in the soil, this material can contaminate the ground water. When he was in the water, this material is not expected to be volatile. | ||
XII. Disposal
| Product Disposal | : | This material must be enclosed and should not be dumped in rivers, drains or waterways. Reproduction of this material to dispose of remaining in environmental media, without prior treatment in accordance with the Government Regulation no. 18 Year 1999 regarding Management of Hazardous and Toxic Waste |
| Disposal containers | : | Empty containers should be cleaned by rinsing with water. Containers that can not be used again should be cleaned from the steam-vapor prior to disposal. Residues may cause an explosion hazard Do not punch a hole, cutting or welding drums that have not been cleaned. Left empty packaging should be used initially or discarded after the Government Regulation No. 18 Year 1999 regarding Management of Hazardous and Toxic Waste |
| Local Regulations | Combustion can be performed by a body approved under controlled conditions if permitted by the authorities, if not removal should be done following the rules on waste and environmental regulations. |
XIII. Transportation Method
Benzyl Alcohol is not classified as hazardous materials according to statutory regulations.
XIV. INFO RELATING TO REGULATION
| Symbol | : | Xn - Harmful | |||||
| R Phrases | R 20/21/22 | Harmful if inhaled, if contact with skin and if swallowed. | |||||
| R 36/37/38 | Irritating to eyes, respiratory system and skin. | ||||||
| Phrases S | : | S 24/25 | Avoid contact with skin and eyes. | ||||
| S26 | If eye contact, rinse immediately with plenty of water and immediately seek medical help. | ||||||
| S36/37/39 | Use protective clothing, gloves and eye protection / face accordingly. | ||||||
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